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procedure TForm1.Button1Click(Sender: TObject);
var
  i, j: Integer;
begin
  with DBGrid1.DataSource.DataSet do
    for i := 0 to DBGrid1.FieldCount - 1 do
      for j := 0 to FieldCount - 1 do
        if Fields[j].FieldName = DBGrid1.Fields[i].FieldName then
          DBGrid1.Columns[i].Title.Alignment := Fields[j].Alignment;
end;